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Colour-coded Piper

How to read a colour-coded Piper diagram

The familiar Piper plot with a twist — every sample takes a colour from its position in the diamond, so you can carry water chemistry straight onto a map.

The gist

A colour-coded Piper is an ordinary Piper plot in which every sample is coloured by its position in the diamond. Chemically similar waters get similar colours — so you can carry that colour straight onto a map, cross-section or time series (Peeters 2014).

It's a Piper, first

Everything about reading a Piper still applies: the cation and anion ternaries project into the central diamond, and where a sample lands names its water type. If that's new, start with the Piper guide — the axes, arrows and percentage scales here are identical.

What the colour adds

Peeters (2014) set out to fix the Piper's main weakness: it is hard to link a sample's position in the plot back to where it sits in the aquifer. The remedy is a continuous background colour field across the diamond. Each sample takes the colour of its diamond position, and you can then colour the same points on a map with the identical colours. A patch of blue on the map instantly reads as fresh Ca–HCO₃ water, a red patch as saline Na–Cl, and the gradients between them as mixing.

20%40%60%80%20%40%60%80%20%40%60%80%← CaMg →Na + K →20%40%60%80%20%40%60%80%20%40%60%80%Cl →← SO₄← HCO₃ + CO₃20%40%60%80%20%40%60%80%20%40%60%80%20%40%60%80%← Ca + MgSO₄ + Cl →colour ≈ water typeCa–ClNa–ClCa–HCO₃Na–HCO₃RecBore-01 · Ca–HCO₃RecBore-02 · Ca–HCO₃MidBore-07 · Mixed–MixedMidBore-09 · Mixed–MixedDeepBore-03 · Na+K–HCO₃CoastBore-02 · Na+K–ClCoastBore-05 · Na+K–ClEvapBore-01 · Mixed–SO₄
The diamond is filled with a continuous colour field; each marker takes the colour of its position, and the two triangles are labelled exactly as on a standard Piper. The key names the four corner water types.

The colour key

The four corners of the diamond are the end-member water types, and the colours blend smoothly between them:

CornerColourWater type
Bottom-leftBlueCa–HCO₃ — fresh recharge
Top-rightRedNa–Cl — saline / seawater
Top-leftAmberCa–Cl
Bottom-rightPurpleNa–HCO₃
Reading tip. The colour is not extra information — it is the sample's diamond position expressed as a hue. Its real value lies outside the Piper: reuse the same colours on a map or long-section and the spatial pattern of water types leaps out.

Watch for

Colour is only as trustworthy as the analysis behind it, so keep an eye on charge balance. Hydrochart fills the diamond with a continuous bilinear blend of the four corner colours — the same idea as Peeters' scheme (turn a diamond position into a reusable colour), though his original uses a perceptually-uniform HSV map, so exact hues differ from his figures. Treat the colour as a spatial-linking aid, and read the water type itself from the diamond position, just as on any Piper.

Authoritative sources & further reading

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